What is the process of oxidation?

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Oxidation is the reaction caused by contact between substances and oxygen molecules. Such substances may be metals or non-metals, such as living tissues.

More technically, oxidation can be defined as the loss of one electron during the phase where two or more elements interact. In this, the elements do not necessarily include oxygen. In short, it can be described as an atom’s enhanced oxidation state via a chemical reaction. It's exact opposite is called reduction, which exhibits a decrease in its oxidation state. Both reactions entail formal electron transfers. Net loss involves oxidation while net gain is the state of reduction.

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Corrosionpedia Explains Oxidation

Oftentimes, oxidation is intertwined with the term "rusting." However, not all substances that come in contact with oxygen crumble into rust. For instance, iron that is exposed to oxygen will undergo a deliberate burning process resulting in rusting. When this reaction occurs with copper, the outcome is called copper oxide, a greenish type of coating. In such a case, the metal is not waned by the oxidation process, but the material surface will form patina years after exposure to water and air. With such, corrosion can be closely associated with oxidation since the process entails bond formation between oxygen and steel. However, oxygen is not the only element that is responsible for the process of oxidation. In dry settings, most materials such as steel do not undergo rusting. The oxidation cause in such cases can be related to the existence of water.

To prevent corrosion caused by oxidation, materials can be guarded through different factory coatings. These may include:

  • High-density polyethylene (HDPE)
  • Fusion-bonded epoxy (FBE)
  • Urethanes

Moreover, field-applied coatings can also be utilized like those that are bitumen based, multiple- or single-layer butyl tapes, petrolatum and others. The type of coating that should be chosen depends on factors like:

  • Environmental settings
  • Expected substrate lifetime
  • Shape, position and substrate material
  • Repair and application costs

By understanding the oxidation process that can be attributed to corrosion, proper coating applications can be facilitated.

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  1. Oxidation and reduction in terms of oxygen transfer
  2. Oxidation and reduction in terms of hydrogen transfer
  3. Oxidation and reduction in terms of electron transfer
  4. Summary

This page discusses the various definitions of oxidation and reduction (redox) in terms of the transfer of oxygen, hydrogen, and electrons. It also explains the terms oxidizing agent and reducing agent.

Oxidation and reduction in terms of oxygen transfer

The terms oxidation and reduction can be defined in terms of the adding or removing oxygen to a compound. while this is not the most robust definition, as discussed below, it is the easiest to remember.

Oxidation and Reduction with respect to Oxygen Transfer

  • Oxidation is the gain of oxygen.
  • Reduction is the loss of oxygen.

For example, in the extraction of iron from its ore:

What is the process of oxidation?

Because both reduction and oxidation are occurring simultaneously, this is known as a redox reaction.

An oxidizing agent is substance which oxidizes something else. In the above example, the iron(III) oxide is the oxidizing agent. A reducing agent reduces something else. In the equation, the carbon monoxide is the reducing agent.

  • Oxidizing agents give oxygen to another substance.
  • Reducing agents remove oxygen from another substance.

Oxidation and reduction in terms of hydrogen transfer

These are old definitions which are no longer used, except occasionally in organic chemistry.

Oxidation and Reduction with respect to Hydrogen Transfer

  • Oxidation is the loss of hydrogen.
  • Reduction is the gain of hydrogen.

Notice that these are exactly the opposite of the oxygen definitions (#1).

For example, ethanol can be oxidized to ethanal:

What is the process of oxidation?

An oxidizing agent is required to remove the hydrogen from the ethanol. A commonly used oxidizing agent is potassium dichromate(VI) solution acidified with dilute sulfuric acid. Ethanal can also be reduced back to ethanol by adding hydrogen. A possible reducing agent is sodium tetrahydridoborate, NaBH4. Again the equation is too complicated to consider at this point.

What is the process of oxidation?

More precise definitionsof oxidizing and reducing agents are

  • Oxidizing agents add oxygen to another substance or remove hydrogen from it.
  • Reducing agents remove oxygen from another substance or add hydrogen to it.

Oxidation and reduction in terms of electron transfer

Oxidation and Reduction with respect to Electron Transfer

  • Oxidation is loss of electrons
  • Reduction is gain of electrons

Remembering these definitions is essential, and easily done using this convenient acronym:

What is the process of oxidation?

Example 1

The equation below shows an obvious example of oxygen transfer in a simple redox reaction:

\[ \ce{CuO + Mg \rightarrow Cu + MgO} \nonumber\]

Copper(II) oxide and magnesium oxide are both ionic compounds. If the above is written as an ionic equation, it becomes apparent that the oxide ions are spectator ions. Omitting them gives:

What is the process of oxidation?

In the above reaction, magnesium reduces the copper(II) ion by transferring electrons to the ion and neutralizing its charge. Therefore, magnesium is a reducing agent. Another way of putting this is that the copper(II) ion is removing electrons from the magnesium to create a magnesium ion. The copper(II) ion is acting as an oxidizing agent.

Summary

Confusion can result from trying to learn both the definitions of oxidation and reduction in terms of electron transfer and the definitions of oxidizing and reducing agents in the same terms. The following thought pattern can be helpful:

  • An oxidizing agent oxidizes something else.
  • Oxidation is loss of electrons (OIL RIG).
  • Therefore, an oxidizing agent takes electrons from that other substance.
  • Therefore, an oxidizing agent must gain electrons.

​Here is another mental exercise:

  • An oxidizing agent oxidizes something else.
  • Therefore, the oxidizing agent must be reduced.
  • Reduction is gain of electrons (OIL RIG).
  • Therefore, an oxidizing agent must gain electrons.


This page titled Definitions of Oxidation and Reduction is shared under a not declared license and was authored, remixed, and/or curated by Jim Clark.

What is oxidation process explain with example?

The term oxidation was originally used to describe reactions in which an element combines with oxygen. Example: The reaction between magnesium metal and oxygen to form magnesium oxide involves the oxidation of magnesium.

What is the oxidation process called?

The chemical reactions which involve the transfer of electrons from one chemical substance to another. These electron-transfer reactions are termed as oxidation-reduction reactions or redox reactions.

What are the 2 processes of oxidation?

Oxidation as a gain of oxygen – An oxidizing agent gives oxygen atoms to another substance in a compound. Oxidation as a loss of hydrogen – An oxidizing agent removes hydrogen atoms from another substance in a compound.

Where the process of oxidation occurs?

Oxidation occurs when an atom, molecule, or ion loses one or more electrons in a chemical reaction. When oxidation occurs, the oxidation state of the chemical species increases. Oxidation doesn't necessarily involve oxygen! Originally, the term was used when oxygen caused electron loss in a reaction.